In Search of Lost Iridium: Quantification of Anode Catalyst Layer Dissolution in Proton Exchange Membrane Water Electrolyzers

نویسندگان

چکیده

Understanding catalyst dissolution pathways in proton exchange membrane water electrolyzers is paramount for developing mitigation strategies aiming toward higher durability and lower loadings. To this end, Ir has been extensively studied using aqueous model systems but not real devices. Aiming to bridge knowledge gap, we use a metal-free electrolysis setup determine the mass balance of dissolved an electrolyzer when applying protocol mimicking intermittent operation. We find that main sinks are cathode layer membrane, while into lines significantly lower. Although reproducible estimation present challenging, quantification within reliable efficient. This new finding implies tracking can be used estimate anode stability, thus accelerating development operational parameters optimization.

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ژورنال

عنوان ژورنال: ACS energy letters

سال: 2023

ISSN: ['2380-8195']

DOI: https://doi.org/10.1021/acsenergylett.3c00193